Impact of suboxia on sinking particulate organic carbon: Enhanced carbon flux and preferential degradation of amino acids via denitrification     

Benjamin A.S Van Mooy  Richard G KeilAllan H Devol 《Geochimica et cosmochimica acta》2002,66(3):457-465

Fluxes of particulate organic carbon (POC) through the oxygen deficient waters in the eastern tropical North Pacific were found to be relatively less attenuated with depth than elsewhere in the eastern North Pacific. The attenuation coefficient (b) for the flux was found to be 0.40 versus the composite value of 0.86 determined by Martin et al. (1987). To examine this further, sinking POC was collected using sediment traps and allowed to degrade in oxic and suboxic experiments. Using a kinetic model, it was found that degradation proceeded at similar rates (roughly 0.8 day⁻¹) under oxic and suboxic conditions, but a greater fraction of bulk POC was resistant to degradation in the suboxic experiments (61% vs. 23%). Amino acids accounted for 37% of POC collected at 75m, but following degradation the value dropped to 17% and 16% in the oxic and suboxic experiments respectively. POC collected from 500m was 10% amino acids. The non-AA component of POC collected at 75m was not degraded under suboxic conditions, while under oxic conditions it was. These results suggest that microbes degrading OC under suboxic conditions via denitrification preferentially utilize nitrogen-rich amino acids. This preferential degradation of amino acids suggests that 9% more nitrogen may be lost via water column denitrification than is accounted for when a more “Redfieldian” stoichiometry for POC is assumed.  相似文献   

Surface chemistry and reactivity of biogenic silica   总被引：2，自引：0，他引：2  

Suvasis Dixit  Philippe Van Cappellen 《Geochimica et cosmochimica acta》2002,66(14):2559-2568

The surface chemistry of cultured diatoms was compared to that of biosiliceous material in Southern Ocean sediments, using potentiometric titrations and aluminum adsorption experiments. Aerosil 200, a well-studied synthetic amorphous silica, served as reference solid. Surface charge development and aluminum adsorption on cultured diatom shells were comparable to Aerosil. The surface chemical properties of biosiliceous material buried to depths of 15-25 cm in Southern Ocean sediments, however, deviated markedly from those of the cultured diatoms. In pH range 4-8.5, the surface charge density was systematically lower for biogenic silica from the sediments. In addition, the aluminum adsorption edge on the biosiliceous sediments was shifted to higher pHs by about 0.4 units. The results indicate that ionizable surface silanol groups on diagenetically altered diatom shells are less abundant and, possibly, less acidic than on freshly cultured diatoms. The observed differences in surface chemical structure are consistent with the progressive loss of reactivity, or aging, of biogenic silica which promotes its preservation in sediments.  相似文献   

U-series dating of bone using the diffusion-adsorption model     

A.W.G. PikeR.E.M. Hedges  P. Van calsteren 《Geochimica et cosmochimica acta》2002,66(24):4273-4286

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Uniform postglacial slip-rate along the central 600 km of the Kunlun Fault (Tibet), from ²⁶Al, ¹⁰Be, and ¹⁴C dating of riser offsets, and climatic origin of the regional morphology     

Jerome Van Der Woerd  Paul Tapponnier  Frederick J. Ryerson  Anne-Sophie Meriaux  Bertrand Meyer  Yves Gaudemer  Robert C. Finkel  Marc W. Caffee  Zhao Guoguang  Xu Zhiqin 《Geophysical Journal International》2002,148(3):356-388

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阿尔金断裂带晚第四纪左旋走滑速率及其构造运动转换模式讨论   总被引：35，自引：2，他引：35  

徐锡伟  P.Tapponnier  J.Van Der Woerd  F.J.Ryerson  王峰  郑荣章  陈文彬  马文涛  于贵华  陈桂华  A.S.Meriaux 《中国科学D辑》2003,33(10):967-974

在高分辨率SPOT卫星数字影像和大比例尺航片处理、断错地貌制图、野外核实与位移测量基础上, 利用宇宙成因核素(¹⁰Be, ²⁶Al)、碳十四(¹⁴C)和热释光(TL)等多种测年手段, 厘定了各断错地貌面的形成年龄, 得到了阿尔金断裂带不同段落全新世左旋走滑速率: 阿克赛以西的中、西段左旋走滑速率可达(17.5±2) mm/a, 肃北-石包城段为(11±3.5) mm/a左右, 疏勒河口段减少到(4.8±1) mm/a左右, 东端宽滩山段仅约(2.2±0.2) mm/a, 左旋走滑速率突变点位于阿尔金断裂带中东段存在分支活动逆断层向南东扩展的肃北、石包城和疏勒河等三联点上. 矢量分析表明, 三联点东、西两侧左旋滑动速率的减少量转换成了阿尔金断裂带中东段南盘北西向活动逆断层上的地壳缩短和上盘推覆体抬升, 形成了党河南山、大雪山、祁连山等条块山地. 因此, 青藏高原北部物质向东挤出的速率和幅度是有限的, 符合“叠瓦状逆冲转换——有限挤出模型”.  相似文献   

Flexural subsidence by 29 Ma on the NE edge of Tibet from the magnetostratigraphy of Linxia Basin, China   总被引：43，自引：0，他引：43  

Xiaomin Fang  Carmala Garzione  Rob Van der Voo  Jijun Li  Majie Fan 《Earth and Planetary Science Letters》2003,210(3-4):545-560

This study provides a detailed magnetostratigraphic record of subsidence in the Linxia Basin, documenting a 27 Myr long sedimentary record from the northeastern edge of the Tibetan Plateau. Deposition in the Linxia Basin began at 29 Ma and continued nearly uninterruptedly until 1.7 Ma. Increasing rates of subsidence between 29 and 6 Ma in the Linxia Basin suggest deposition in the foredeep portion of a flexural basin and constrain the timing of shortening in the northeastern margin of the plateau to Late Oligocene–Late Miocene time. By Late Miocene–Early Pliocene time, a decrease in subsidence rates in the Linxia Basin associated with thrust faulting and a 10° clockwise rotation in the basin indicates that the deformation front of the Tibetan plateau had propagated into the currently deforming region northeast of the plateau.  相似文献   

Middle Paleozoic paleomagnetism of east Kazakhstan: post-Middle Devonian rotations in a large-scale orocline in the central Ural–Mongol belt     

Natalia M. Levashova  Kirill E. Degtyarev  Mikhail L. Bazhenov  Adam Q. Collins  Rob Van der Voo   《Tectonophysics》2003,377(3-4):249-268

In order to test different hypotheses concerning the Paleozoic evolution of the Ural–Mongol belt (UMB) and the amalgamation of Eurasia, we studied Middle Devonian basalts from two localities (11 sites) and Lower Silurian volcanics, redbeds, and intra-formational conglomerates from three localities (20 sites) in the Chingiz Range of East Kazakhstan. The Devonian rocks prove to be heavily overprinted in the late Paleozoic, and a high-temperature, presumably primary, southerly, and down component is isolated at only four sites from a homoclinal section. Most Silurian redbeds are found to be remagnetized in the late Paleozoic; in contrast, a bipolar near-horizontal remanence, isolated from Silurian volcanics, is most probably primary as indicated by positive tilt and conglomerate tests. Analysis of paleomagnetic data from the Chingiz Range shows that southward-pointing directions in Ordovician, Silurian, and Devonian rocks are of normal polarity and hence indicate large-scale rotations after the Middle Devonian. The Chingiz paleomagnetic directions can be compared with Paleozoic data from the North Tien Shan and with the horseshoe-shaped distribution of subduction-related volcanic complexes in Kazakhstan. Both paleomagnetic and geological data support the idea that today's strongly curved volcanic belts of Kazakhstan are an orocline, deformed mostly before mid-Permian time. Despite the determination of nearly a dozen new Paleozoic paleopoles in this study and other recent publications by our team, significant temporal and spatial gaps remain in our knowledge of the paleomagnetic directions during the middle and late Paleozoic. However, the paleomagnetic results from the Chingiz Range and the North Tien Shan indicate that these areas show generally coherent motions with Siberia and Baltica, respectively.  相似文献   

The Cretaceous and younger thermal history of the KTB site (Germany): apatite fission-track data from the Vorbohrung     

D. A. Coyle  G. A. Wagner  E. Hejl  R. Brown  P. Van den Haute 《International Journal of Earth Sciences》1997,86(1):203-209

A detailed fission-track analysis was carried out on 41 apatite samples from the 4001-m-deep pilot hole of the German Continental Deep Drilling Program (KTB). The investigations include dating by the population method and length measurements of horizontal confined tracks. Age and length information indicate that all samples above the present-day partial annealing zone cooled from temperatures above 120?°C in the Cretaceous. The top two kilometres of the profile show less variation of age with depth than was expected. Modelling of the profile indicates that the distribution of fission track ages with depth requires that the profile was disturbed during or after cooling through the partial annealing zone. Modelling of individual samples reveals that at least the upper 2?km experienced reverse faulting, effectively thickening the upper part of the rock column by up to 1000?m in the Tertiary. A present-day partial annealing zone for apatite was observed between 2000 and 4000?m (～60–110?°C). This confirms earlier in situ observations of the position of the partial annealing zone.  相似文献   

Mechanical aspects of sedimentary basin formation: development of integrated models for lithospheric and surface processes   总被引：1，自引：0，他引：1  

S. Cloetingh  R. T. Van Balen  M. Ter Voorde  B. P. Zoetemeijer  T. Den Bezemer 《International Journal of Earth Sciences》1997,86(2):226-240

Different assumptions for the thermo-mechanical properties of the lithosphere strongly affect predictions inferred from quantitative sedimentary basin modeling. Examples from various basins, selected as natural laboratories, illustrate the importance of incorporating a finite strength of the extending lithosphere in forward stratigraphic modeling of large-scale basin stratigraphy. Current models can effectively couple erosion at uplifted rift shoulders of extensional basins with the basin fill architecture of the subsiding basin compartments. Modeling of the synrift strata integrates spatial scales characteristic for subbasins, such as the Oseberg field in the North Sea, with large-scale lithospheric properties characterizing the bulk strength of extending lithosphere. Modeling of compressional basins in foreland fold-and-thrust-belt settings can effectively link lithospheric flexure with surface processes. Scales pertinent to short-term spatial and temporal variations in basin fill and basin deformation can now be addressed, allowing the quantitative investigation of consequences of different modes of thrusting for basin fill geometry and facies characteristics.  相似文献   

Water-quality trends in White Rock Creek Basin from 1912-1994 identified using sediment cores from White Rock Lake reservoir, Dallas, Texas   总被引：2，自引：0，他引：2  

Peter C. Van Metre  Edward Callender 《Journal of Paleolimnology》1997,17(2):239-239

Historical trends in selected water-quality variables from 1912 to 1994 in White Rock Creek Basin were identified by dated sediment cores from White Rock Lake. White Rock Lake is a 4.4-km² reservoir filled in 1912 and located on the north side of Dallas, Texas, with a drainage area of 259 km². Agriculture dominated land use in White Rock Creek Basin before about 1950. By 1990, 72% of the basin was urban. Sediment cores were dated using cesium-137 and core lithology. Major element concentrations changed, and sedimentation rates and percentage of clay-sized particles in sediments decreased beginning in about 1952 in response to the change in land use. Lead concentrations, normalized with respect to aluminum, were six times larger in sediment deposited in about 1978 than in pre-1952 sediment. Following the introduction of unleaded gasoline in the 1970s, normalized lead concentrations in sediment declined and stabilized at about two and one-half times the pre-1952 level. Normalized zinc and arsenic concentrations increased 66 and 76%, respectively, from before 1952 to 1994. No organochlorine compounds were detected in sediments deposited prior to about 1940. Concentrations of polychlorinated biphenyls (PCB) and DDE (a metabolite of DDT) increased rapidly beginning in the 1940s and peaked in the 1960s at 21 and 20 µg kg^-1, respectively, which is coincident with their peak use in the United States. Concentrations of both declined about an order of magnitude from the 1960s to the 1990s to 3.0 and 2.0 µg kg^-1, respectively. Chlordane and dieldrin concentrations increased during the 1970s and 1980s. The largest chlordane concentration was 8.0 µg kg^-1 and occurred in a sediment sample deposited in about 1990. The largest dieldrin concentration was 0.7 µg kg^-1 and occurred in the most recent sample deposited in the early 1990s. Agricultural use of chlordane and dieldrin was restricted in the 1970s; however, both were used as termiticides, and urban use of chlordane continued at least until 1990. Recent use of dieldrin and aldrin, which degrades to dieldrin, has not been reported; however, increasing trends in dieldrin since the 1970s suggest recent urban use could have occurred.  相似文献